Theses and Dissertations

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Theses and Dissertations (Agricultural and Environmental Engineering)

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  • Item
    Open Access
    Simulating Soil and Groundwater Contamination by Copper and Manganese from Agricultural Fungicides
    (2015-05-14) Osunbitan, Jimmy Akinfemi
    This work developed predictive models that simulated the transportation of copper and manganese from agricultural fungicides through the soil profile as well as the adsorption of the metals to the soil particles. The experiment was conducted in two stages and these stages were Batch Equilibrium Test (BET) and Soil leaching experiment. The BET was conducted as 2 x 4 x 6 factorial experiment. The variables were soil types (Egbeda and Apomu), pH and fungicide concentration. The leaching experiment was conducted as 2 x 3 factorial experiments. The variables were soil type (Egbeda and Apomu) and fungicide concentration. For Batch Equilibrium test, air-dried soil sample of about 1 g was equilibrated with 10 ml solution containing the desired concentrations of the fungicide in a centrifuge. After equilibration and centrifugation, the supernatant were analysed for copper and manganese using Atomic Absorption Spectrophotometer (AAS). Absorption was then estimated from the decrease in the concentration of the metals in the fungicide in the liquid phase after equilibration. For the column leaching experiment, soil columns were wetted at the rate of about 5 mm/h for 1 day. After saturation, the fungicides were applied and the columns kept completely saturated with water by maintaining ponding through continuous application of de – ionized water at a rate of about 10 mm/hr for the duration of the experiment. Leachate samples were collected every 6 hours for 7 days and the leachate analysed for copper and manganese using AAS. Data were analysed using descriptive and inferential statistics. Data from the BET and column leaching experiment were used to modify and validate relevant models. The result of the BET showed that the equilibrium metal concentrations in the soil solution increased significantly with increasing metal concentration in the solution (P < 0.05). The solution pH was significant (P <0.05) in its effect on the amount of metals adsorbed into the soil and the two soils were also significantly different (P < 0.05) in their adsorption capacity. The adsorbed metal increased with increase in solution pH and metal concentration with the maximum adsorption capacities at pH 6 and metal concentrations of 4.50 g/l and 1.44 g/l for Copper and Manganese respectively. Adsorption of copper into Egbeda and Apomu soils was best explained with Langmuir equation with r2 = 0.99 and 0.97 respectively while Freudlich equation was the best model that explained the adsorption of manganese to the two soil types (r2 = 0.95). The results of the leachate experiment showed that the factors considered were all significant (P < 0.05) in their effects on the concentration of the metals in the leachate. Furthermore, the result showed that the developed model was able to simulate the relative metal concentrations in the leachate. The r2 ranges for Copper and Manganese were 0.95 to 0.99 and 0.71 to 0.98 respectively. The estimated values of the solute velocity and dispersion coefficient were also within the 95% Confidence Interval of the breakthrough curves estimates. The study concluded that the developed model predicted well the fate of the metals in the soil - water environment when fungicides are applied to the soil.
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    Open Access
    Effect of Irrigation Systems on Yield and Water Use of Okra and Amaranthus Hybridus
    (2015-05-08) Olanusi, Olaniran Abdul
    The study investigated the growth and yield of okra and Amaranthus hybridus under four irrigation systems, in order to determine the most economical system in terms of water use efficiency, cost inputs, and optimal crop yield. Four irrigation systems, namely, sprinkler, drip, basin and furrow systems were designed and established for the study. The research was carried out using a completely randomised block design of 4 treatments and 3 replicates giving a total of 12 sub-plots with each sub-plot measured 10 m x 8 m. Irrigations were carried out when the available water at the crop root zone depleted to 50% of the soil moisture at field capacity. The soil moisture was monitored using the gravimetric sampling method. Pan evaporation method and the Penman equation were used to determine evapotranspiration. The plant height, leaf counts, leaf area, leaf area index and yield components were measured at different stages of plant growth. The data obtained were subjected to descriptive and inferential statistical analysis to compare crop performance under the different irrigation systems. Engineering economic analysis of growing okra and Amaranthus hybridus under the different irrigation systems was also carried out. The results indicated that okra and Amaranthus hybridus responded well to drip irrigation system when compared to other systems. Drip system gave the largest leaf area of 56.23 cm2 at the end of the third week of the planting. The least leaf area was observed in Amaranthus hybridus grown under the furrow irrigation system. The difference in leaf area of Amaranthus hybridus grown under all the irrigation systems was significant (P<0.05, F=163.38). The highest yield (1875 kg/ha) of Amaranthus hybridus was obtained under the drip irrigation system, while the least (1250 kg/ha) was obtained under furrow irrigation system. A similar trend was obtained for okra, with the highest and least yield of 1551 kg/ha and 972 kg/ha for drip and furrow systems. respectively. The total irrigation water applied to Amaranthus hybridus under the sprinkler, drip, basin and furrow systems was 53, 49, 91 and 74 mm, and these gave water use efficiencies of 32.5, 38.0, 15.2 and 16.9 kg/mm, respectively. The benefit-cost ratios were 0.6, 1.0, 0.7 and 0.7, for sprinkler, drip, basin, and furrow irrigation systems, respectively. On okra plots, the water use efficiency of total irrigation values applied for sprinkler, drip, basin and furrow systems were 3.9, 5.7, 2.4 and 2.2 kg/mm, respectively. The benefit-cost ratios were calculated to be 0.5, 1.1 , 0.8 and 0.7 for sprinkler,'drip. basin and furrow irrigation systems in that order. The cost recovery factor ratio was 4.2, the annual energy cost factor 1.0008, and the annual depreciation cost was N215.08. The study concluded that drip irrigation system was the best in terms of benefit – cost ratio, yield and water use efficiency for both crops.
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    Open Access
    Development of a Composting Chamber for the Reduction of Nitrogen Loss in Poultry Litter
    (2015-04-30) Ogunwande, Gbolabo Abidemi
    The study was undertaken to develop a chicken litter composting chamber and investigate the effects of turning frequency (TF) and carbon to nitrogen (C:N) ratio on the loss of nitrogen (N) in chicken litter piles. This was with a view to producing good quality compost. The experimental set up was a 3 X 3 factorial design with turning frequencies at every 2, 4 and 6 days, and C:N ratios at 20:1, 25:1 and 30:1. The organic materials were composted in a chamber of size 1.2 m x 1.2 m square base and a height of 0.3 m. Each treatment was replicated thrice and turned manually using a hand shovel. During the composting process, the moisture content in the piles was periodically replenished to 55%. The temperature, moisture content (MC), pH, ash, total nitrogen (N), total carbon (C) and C:N ratio of the chicken litter were periodically monitored. The total phosphorus (P) and total potassium (K) contents were determined at the end of composting. Cumulative losses of N and C were quantified to determine actual losses during composting. The data obtained were analyzed using inferential statistics. The results showed that the developed chamber was effective for composting as indicated by the attainment of thermophilic temperatures during the 87 days of composting. It also showed that 'TF and C:N ratio had significant effect (p < 0.05) on moisture loss (F2, 2 4 = 55.24 and 44.32), C (F2, 24 = 68.51 and 35.86), N (F2, 24 = 90.23 and 99.57) and C:N ratio (F2, 24 = 215.35 and 184.94) while temperature was only affected by the C:N ratio (F2, 24 = 7.57, p < 0.05) and pH affected by the T F ( F 2 , 2 4 = 4.63, p < 0.05). Losses of N, which were attributed to volatilization of ammonia (NH3), were highest during the period when the litter temperatures were above 33 °C and the pH values above 7.7. The losses of C were attributed to organic matter (OM) degradation. At the end of composting, TF of 4 days with C:N ratio 25:1 (T4R25) gave the minimum N loss (45.77% of the initial N) resulting in the lowest C:N ratio (24:1) as required of good quality compost while TF of 6 days with C:N ratio 20:1 (T6R20) gave the minimum C loss (41.40% of the initial C). In conclusion, the study showed that good quality compost could be produced using the chamber developed with 4 days TF and initial C:N ratio of 25:1.
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    Open Access
    Optimization of Thermal Comfort in a Naturally Ventilated Livestock Building
    (2015-04-29) Ogunjimi, Lawrence Abiodun Ogunsola
    This work investigated the effect of building vent and orientation on the thermal comfort of rabbits under a naturally ventilated livestock building. This was with a view to optimizing the productivity of the animals. Mathematical equations were used to estimate heat and moisture production by the animals, airflow rate and the Temperature-Humidity Index (THI) of the building. The experiment was conducted using two model buildings oriented at 45° and 90° to the northeast wind. Two inlet vents of 30% and 50% on the windward side and an outlet opening of 20% on the leeward side of the model buildings were used. The experiment was carried out using a 3 x 2 x 2 factorial arrangement with two replicates. The factors were inlet opening, orientation and sex of the animal. A rabbitry without wall on all sides was used as the control building. Data on temperature and relative humidity within and outside the buildings were collected twice daily (7.00 a.m. and 1.00 p.m) and used to calculate the THI. Rabbit weight gain and feed consumption were collected while feed utilization efficiency was calculated on weekly basis. Physiological parameters of pulse rate, rectal temperature and respiration rate were also collected twice a week. The data were analysed using inferential statistics. The results showed that the amount of building opening (difference in the height to length) and orientation significantly (P < 0.01) affected the thermal comfort level of a livestock building. The average THI values were 33.16°C oC, 34.80 °C and 34.33 °C respectively for 50%, 30% and the control (100% opening) buildings, respectively. The building orientation also had significant effect (P < 0.01) on the productivity characteristics of the rabbits. Also, THI were 33.35 °C and 34.61 °C for the 90° and 45° building orientations, respectively. This was attributed to the variations in heat and moisture removal from the buildings. The weight gain and feed efficiency of rabbits in the 90° orientation building were respectively 7.53 g and 0.03 higher than those for 45° orientation building. However, the pulse rate, rectal temperature and respiration rate were 6.95 bpm, 0.84 °C and 6.54 rpm lower in the 90° orientation building than the 45° orientation respectively. Female rabbits also responded better than male rabbits (P < 0.01) with average of 0.61 g and 0.01 higher values of weight gain and feed efficiency, respectively. In conclusion, the study showed that both building orientation with respect to the direction of the prevailing wind and size of ventilating opening affected the Thermal Comfort Indicator (THI).The combination of 50% opening and 90° orientation of the buildings gave the best THI value of 32.49 °C. Under all conditions, the female rabbits responded better than the male in the production characteristics.
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    Open Access
    Effect of Rainwater Harvesting Technology on Cowpea Yield in the Savannah Belt of Nigeria
    (2015-04-17) Balogun, James Adebayo
    This study investigated the effects of two rainwater harvesting (RWH) technologies (micro) and macro-catchments) on cowpea yield in the savannah belt of Nigeria with a view to identifying the better technology that could mitigate against adverse effects of erratic rainfall. The study was carried out in Afikuyomi village (between latitude 7° 45' N and longitude 4° 10' E) 10km north of Iwo town (Osun state) in the derived savannah belt of Nigeria. In the micro catchments RWH, both the runoff producing area (RPA) and runoff receiving area (RRA) lie typically within a single farmland while in the macro catchment system, the two areas (RPA) and RRA) do not lie within a single farmland. The micro catchment plot has a slope of 2° and four treatments: RWH, Semi-circular bunds (SCB), Semi-circular bunds with RWH (SCB+RWH) and the control plot. The experimental layout was completely randomized with three replicates of each treatment. Each of the four sub plots measured 7m x 5m. The macro catchment plot was made up of four treatments: Double soil manipulation (DSM) with RWH (DSM+RWH), Single soil manipulation (SSM) with RWH (SSM+RWH), Zero tillage (ZT) with RWH (ZT+RWH) and the control plot laid out in complete randomized design with two replicates. Each of the four sub-plots measured 5m x 5m. Plant and soil parameters were measured fortnightly during the growing period. At maturity, yield and its components were determined. The results showed that in the micro catchment plot, the average soil moisture content were 10.95%, 10.08%, 8.90% and 7.69% in the SCB+RWH, RWH, SCB and control treatments respectively at 0-15cm,15-30cm and 30-45cm depths. The highest crop yield of 0.47t/ha and 1.55/ha dry matter were obtained for the SCB+RWH treatment compared to 0.31t/ha and 1.18t/ha for the control. Furthermore, the SCB treatment had the highest water use efficiency value of 7.7okg/hacm-1 compared with 6.09kg/hacm for the RWH p<0.05). In the macro plot, DSM+RWH gave the least soil penetration resistance of 6.8N and bulk density of 1.50g/cm3 compared with 30.75N and 1.61 g/cm3 for the control treatment. Also, the highest crop yield of 1.84t/ha, 3.3t/ha dry matter and 26.52kg/ha cm-1 water use efficiency (P<0.05) were obtained for DSM+RWH compared with 0.78t/ha and 2.64t/ha for the control and 13.0kg/hacm-1 water use efficiency for the ZT+RWH treatment. The results showed that cowpea yield can be increased using either micro-catchment RWH with Semi-circular bunds (RWH+SCB) or Macro catchment RWH with double soil manipulation (RWH+DSM).